Behavior of stabilized multiwalled carbon nanotubes in a FeCl3 coagulation system and the structure characteristics of the produced flocs

He, M; Zhou, R; Guo, X

HERO ID

955027

Reference Type

Journal Article

Year

2012

Language

English

PMID

22014394

HERO ID 955027
In Press No
Year 2012
Title Behavior of stabilized multiwalled carbon nanotubes in a FeCl3 coagulation system and the structure characteristics of the produced flocs
Authors He, M; Zhou, R; Guo, X
Journal Journal of Colloid and Interface Science
Volume 366
Issue 1
Page Numbers 173-178
Abstract The understanding of the fate and the transport of carbon nanotubes (CNTs) in the water treatment process will provide important information for assessing the environmental risks of CNTs. To fill the knowledge gap, this study investigated the removability of multiwalled carbon nanotubes (MWNTs) stabilized by humic acid (HA) during the coagulation-flocculation-sedimentation (CFS) process. The structure characteristics of the produced flocs were systematically investigated using a variety of characterization approaches. The configuration resembling a root-soil system is shown in the images of scanning and transmission electron microscopy (SEM and TEM). With the incorporation of HA-MWNTs into the produced flocs, the X-ray diffraction (XRD) patterns of MWNTs completely disappeared. Fourier transform infrared spectra (FT-IR) and Mössbauer spectra suggested that the intervention of HA-hinged MWNTs increased the degree of polymerization and the particle size of the produced hydrous ferric oxide (HFO). Finally, both the effective sequestration of MWNTs by CFS demonstrated here and the high sorption capacity of MWNTs for phenanthrene implied that MWNTs might be used as a potential coagulant aid in water processing for the enhanced removal of hydrophobic organic chemicals.
Doi 10.1016/j.jcis.2011.09.059
Pmid 22014394
Wosid WOS:000297385900025
Is Certified Translation No
Dupe Override No
Comments Scopus URL: https://www.scopus.com/inward/record.uri?eid=2-s2.0-80655133071&doi=10.1016%2fj.jcis.2011.09.059&partnerID=40&md5=5f66525aec3f1c1afcb575a8b29d1d1d
Is Public Yes
Language Text English
Keyword Coagulation; Flocs; Mössbauer spectra; Multi-wall carbon nanotubes (MWNTs); Removal
Is Qa No