Discussion of thermodynamic data obtained by adsorption gas chromatography of hydrocarbons on a new graphitized carbon black with a high specific surface area

Mastrogiacomo, AR; Pierini, E

HERO ID

4968776

Reference Type

Journal Article

Year

2000

HERO ID 4968776
In Press No
Year 2000
Title Discussion of thermodynamic data obtained by adsorption gas chromatography of hydrocarbons on a new graphitized carbon black with a high specific surface area
Authors Mastrogiacomo, AR; Pierini, E
Journal Chromatographia
Volume 51
Issue 7-8
Page Numbers 455-460
Abstract A new graphitized carbon black (Carbograph 5) with a specific surface area (560 m(2) g(-1)) greater than those of commercially available graphitized carbons was studied by gas chromatography to determine the enthalpy, entropy, and free energy of adsorption of a series of alkanes (C-2-C-6) The adsorption properties were also investigated by considering changes in the isosteric heats and entropies of adsorption when a nonpolar stationary phase (squalane) was added to the adsorbent. The data obtained are discussed and compared with literature values for other graphitized carbon blacks.
Doi 10.1007/BF02490484
Wosid WOS:000086898300013
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword gas chromatography; graphitized carbon black; adsorbents; thermodynamic data