Distribution of isoprenoid hydrocarbons and alkylbenzenes in immature sediments - evidence for direct inheritance from bacterial algal sources

Vella, AJ; Holzer, G

HERO ID

4968775

Reference Type

Journal Article

Year

1992

Language

English

HERO ID 4968775
In Press No
Year 1992
Title Distribution of isoprenoid hydrocarbons and alkylbenzenes in immature sediments - evidence for direct inheritance from bacterial algal sources
Authors Vella, AJ; Holzer, G
Journal Organic Geochemistry
Volume 18
Issue 2
Page Numbers 203-210
Abstract Alkanes having unusual saturated isoprenoidal and methyl-branched structures have been isolated from the bitumen of several sediments. The methanogenic biomarkers 2,6,10,15,19-pentamethyleicosane and squalane were found in sediments which also contained bacteriogenic glycerol ethers. However, in one ether-containing sediment, 2,6,10,13,17,21 -hexamethyldocosane was tentatively identified and this compound was found in place of the established alkane biomarkers. Other hydrocarbons found were regular C21 and C23 isoprenoid alkanes, compounds which cannot be derived from phytol; two isoprenoids of the type 3,7,11 . . . -polymethylalkane, previously reported only in petroleums; 8-methylheptadecane, a probable biomarker for cyanobacteria and a number of its homologs and other methyl-branched alkanes. Ubiquitous branched-chain alkylbenzenes and a homology of trimethylalkylbenzenes were also isolated. Most, or all, of the compounds reported here are probably not catagenetic products but may represent direct algal or bacterial bioinputs.
Doi 10.1016/0146-6380(92)90131-G
Wosid WOS:A1992HR56000008
Url http://linkinghub.elsevier.com/retrieve/pii/014663809290131G
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English
Keyword LIPIDS; BIOMARKERS; BRANCHED ALKANES; ALKYLBENZENES