An investigation of the formation mechanism of allene or alkyne in the 6,7-benzobicyclo[3,2.1]octane system by deuterium labeling experiments
Taskesenligil, Y; Tumer, F; Kazaz, C; Balci, M
| HERO ID | 4854521 |
|---|---|
| In Press | No |
| Year | 1999 |
| Title | An investigation of the formation mechanism of allene or alkyne in the 6,7-benzobicyclo[3,2.1]octane system by deuterium labeling experiments |
| Authors | Taskesenligil, Y; Tumer, F; Kazaz, C; Balci, M |
| Journal | Turkish Journal of Chemistry |
| Volume | 23 |
| Issue | 2 |
| Page Numbers | 115-122 |
| Abstract | In order to reveal the real intermediate in the base-promoted reaction of 1, 3-bromo-4,4-dideuterio-6,7-benaobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied. Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured. |
| Wosid | WOS:000080833000001 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | cyclic allene; cyclic alkynes; deuterium labeling |