On the synthesis of beta-bromohydrine ethers via intermolecular alkoxyl radical addition to bicyclo[2.2.1]heptene
Hartung, J; Schneiders, N; Gottwald, T
| HERO ID | 4854510 |
|---|---|
| In Press | No |
| Year | 2007 |
| Title | On the synthesis of beta-bromohydrine ethers via intermolecular alkoxyl radical addition to bicyclo[2.2.1]heptene |
| Authors | Hartung, J; Schneiders, N; Gottwald, T |
| Journal | Tetrahedron Letters |
| Volume | 48 |
| Issue | 34 |
| Page Numbers | 6027-6030 |
| Abstract | Primary, secondary, and tertiary alkoxyl radicals add exo-selectively to the olefinic pi-bond in bicyclo[2.2.1]heptene to afford exo-2-alkoxybicyclo[2.2.1]kept-3-yl radicals, which are trapped with BrCCl3 preferentially from the endo face to furnish beta-bromohydrine ethers in 23-67% yield. (c) 2007 Elsevier Ltd. All rights reserved. |
| Doi | 10.1016/j.tetlet.2007.06.103 |
| Wosid | WOS:000248985600024 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |