Chromatographic models for the sorption of neutral organic compounds by soil from water and air
Poole, SK; Poole, CF
HERO ID
645740
Reference Type
Journal Article
Year
1999
Language
English
PMID
| HERO ID | 645740 |
|---|---|
| In Press | No |
| Year | 1999 |
| Title | Chromatographic models for the sorption of neutral organic compounds by soil from water and air |
| Authors | Poole, SK; Poole, CF |
| Journal | Journal of Chromatography A |
| Volume | 845 |
| Issue | 1-2 |
| Page Numbers | 381-400 |
| Abstract | The solvation parameter model is used to construct models for the estimation of the soil-water and soil-air distribution constants and to characterize the contribution of fundamental intermolecular interactions to the underlying sorption processes. Wet soil is shown to be quite cohesive and polar but relatively non-selective for dipole-type, lone-pair electron and hydrogen-bond interactions. Using a comparison of system constant ratios chromatographic systems employing reversed-phase liquid chro chromatographic model reproduce experimental distribution constants for a wide variety of compoundswith a similar error (0.2-0.3 log units) to that expected in the experimental data. |
| Doi | 10.1016/S0021-9673(98)01085-1 |
| Pmid | 10399340 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |
| Keyword | Mathematics; Statistics; Biology; Biochemistry methods; Biophysics methods; Air pollution; Soil pollutants; Water pollution |
| Relationship(s) |
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