Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8 : 2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals
Chiappero, MS; Arguello, GA; Hurley, MD; Wallington, TJ
| HERO ID | 603172 |
|---|---|
| In Press | No |
| Year | 2008 |
| Title | Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8 : 2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals |
| Authors | Chiappero, MS; Arguello, GA; Hurley, MD; Wallington, TJ |
| Journal | Chemical Physics Letters |
| Volume | 461 |
| Issue | 4-6 |
| Page Numbers | 198-202 |
| Abstract | Smog chamber/FTIR techniques were used to measure a 92 +/- 7% yield of C8F17CH2CHO in the chlorine atom initiated oxidation of C8F17CH2CH2OH ( 8: 2 FTOH) in 700 Torr of air. Relative rate techniques were used to measure k(Cl + C8F17CH2CHO) = (1.9 +/- 0.4) x 10 (11) and k(OH + C8F17CH2CHO) = (2.0 +/- 0.4) x 10 (12) cm(3) molecule (1) s (1) in 700 Torr of N-2 or air diluent at 296 K. The results are discussed with respect to the atmospheric chemistry of fluorotelomer alcohols. (C) 2008 Elsevier B.V. All rights reserved. |
| Doi | 10.1016/j.cplett.2008.06.088 |
| Wosid | WOS:000258395300005 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Is Qa | No |