Predicting the sorption of fatty alcohols and alcohol ethoxylates to effluent and receiving water solids

van Compernolle, R; Mcavoy, DC; Sherren, A; Wind, T; Cano, ML; Belanger, SE; Dorn, PB; Kerr, KM

HERO ID

5097198

Reference Type

Journal Article

Year

2006

Language

English

PMID

16338005

HERO ID 5097198
In Press No
Year 2006
Title Predicting the sorption of fatty alcohols and alcohol ethoxylates to effluent and receiving water solids
Authors van Compernolle, R; Mcavoy, DC; Sherren, A; Wind, T; Cano, ML; Belanger, SE; Dorn, PB; Kerr, KM
Journal Ecotoxicology and Environmental Safety
Volume 64
Issue 1
Page Numbers 61-74
Abstract Alcohol ethoxylates (AEs) are an important group of nonionic surfactants. Commercial AEs consist of a mixture of several homologues of varying carbon chain length (Cx) and degree of ethoxylation (EOy). The major disposal route of AE is down the drain to municipal wastewater treatment plants that discharge into receiving surface waters. Sorption of AE homologues onto activated sludge and river water solids is an important factor in assessing exposure of AE in the environment. This study presents the experimental determination of sorption coefficients for a wide array of AE homologues including five alcohols under environmentally relevant conditions and combines these data with literature data to generate a predictive model for the sorption of AEs in the environment. These results demonstrate that sorption can be effectively modeled using a log Kd vs. Cx and EOy predictive equation having the form log Kd = 0.331C - 0.00897EO - 1.126(R2 = 0.64).
Doi 10.1016/j.ecoenv.2005.10.013
Pmid 16338005
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English