Comparative effects of oxygenates-gasoline blended fuels on the exhaust emissions in gasoline-powered vehicles

Lim, CS; Lim, JH; Cha, JS; Lim, JY

HERO ID

5068483

Reference Type

Journal Article

Year

2019

Language

English

PMID

30897476

HERO ID 5068483
In Press No
Year 2019
Title Comparative effects of oxygenates-gasoline blended fuels on the exhaust emissions in gasoline-powered vehicles
Authors Lim, CS; Lim, JH; Cha, JS; Lim, JY
Journal Journal of Environmental Management
Volume 239
Page Numbers 103-113
Abstract This study aimed to investigate the comparative effects of oxygenates such as ethanol (EA), methyl tertiary-butyl ether (MTBE), and ethyl tertiary butyl ether (ETBE) by fixing the oxygen contents as 0.82 wt% 1.65 wt%, and 2.74 wt% of the fuels on the regulated (CO, NMHC and NOx) and unregulated (formaldehyde, acetaldehyde and BTEX) exhaust emissions in gasoline-powered vehicles. The most widely used type of vehicles (light-duty, medium-duty, heavy-duty) in Korea were tested on a chassis dynamometer under the CVS-75 Cycle. When EA, MTBE and ETBE percentage increased, the CO and NMHC concentration decreased. The NOx emission decreased at 1.65 wt% and 2.74 wt% oxygen content of MTBE and ETBE. The emissions of CO decreased by 0.363 g/km, 0.266 g/km and 0.356 g/km for light-duty vehicle when EA, MTBE and ETBE oxygenates blending ratio increased. Increased EA, MTBE and ETBE oxygenates blending ratio demonstrated no specific reducing effect on CO emissions from low-mileage vehicle, but NMHC emissions decreased by 0.011 g/km (medium-duty), 0.015 g/km (light-duty) and 0.018 g/km (heavy-duty). More CO was emitted from MTBE among three oxygenates at same oxygen content. The emitted concentrations of NMHC from three oxygenates at same oxygen content were almost similar, but reduced NOx emissions from EA (10%) to MTBE (20.4%) and ETBE (23.6%) were observed at 2.74 wt% oxygen content. Reducing effect on CO emissions was order of EA > ETBE > MTBE. Formaldehyde emissions increased up to 54.3% as MTBE ratio increased. When oxygen content of ETBE, EA, and MTBE increased from 0.82 wt% to 2.74 wt%, the acetaldehyde emissions increased up to 177.4%, 39.5% and 31.0%, respectively. There was significant formaldehyde concentration difference between high emission vehicle type (light-duty and medium-duty) and low emission vehicle type (heavy-duty and low-mileage) for three oxygenates. Reduction effect of MTBE and ETBE on BTEX was the order of toluene > benzene > ethylbenzene > xylene, and MTBE showed more reduction effect than ETBE at same oxygen content.
Doi 10.1016/j.jenvman.2019.03.039
Pmid 30897476
Wosid WOS:000465366100013
Url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85063345593&doi=10.1016%2fj.jenvman.2019.03.039&partnerID=40&md5=d764c6f4be64d27bda21c60c3bdbbb9c
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English
Keyword Ethanol; MTBE; ETBE; Oxygen content; Regulated and unregulated exhaust emissions; Gasoline-powered vehicle