Autoxidation of dipropylene glycol isomers
Janik, R; Gerhardt, W
HERO ID
4949131
Reference Type
Journal Article
Year
1989
Language
English
| HERO ID | 4949131 |
|---|---|
| In Press | No |
| Year | 1989 |
| Title | Autoxidation of dipropylene glycol isomers |
| Authors | Janik, R; Gerhardt, W |
| Journal | Journal für Praktische Chemie |
| Volume | 331 |
| Issue | 4 |
| Page Numbers | 611-616 |
| Abstract | The oxidative decomposition of two structural isomers of dipropylene glycol, i.e. 2,4‐dimethyl‐3‐oxapentandiol‐1,5 (1) and 4‐oxaheptandiol‐2,6 (2) was studied. The maximum rate of oxidation of glycol 1 was ca. 20 times lower than that of glycol 2. In the products of oxidation 15 different compounds were detected for the former glycol and 20 compounds for the latter. The products of decomposition were the mixtures of water and carboxy acid, acetal, alcohol, aldehyde, ketone, ester, unsaturated ether and hydroperoxy type of compounds of different structure. The mechanism of product formation is discussed. |
| Doi | 10.1002/prac.19893310410 |
| Wosid | WOS:A1989CF45600008 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |