The particular sensitivity of silyl ethers of D-glucal toward two Vilsmeier-Haack reagents POCl3.DMF and (CF3SO2)2O.DMF. Their unique and selective conversion to the corresponding C(6)-O-formates
Lellouche, JP; Koeller, S
| HERO ID | 4947003 |
|---|---|
| In Press | No |
| Year | 2001 |
| Title | The particular sensitivity of silyl ethers of D-glucal toward two Vilsmeier-Haack reagents POCl3.DMF and (CF3SO2)2O.DMF. Their unique and selective conversion to the corresponding C(6)-O-formates |
| Authors | Lellouche, JP; Koeller, S |
| Journal | Journal of Organic Chemistry |
| Volume | 66 |
| Issue | 3 |
| Page Numbers | 693-696 |
| Abstract | The two electrophilic Vilsmeier-Haack reagents POCl3.DMF 2 or (CF3SO2)2O.DMF 3 mediate the one-step and selective conversion of O-triethylsilyl (O-TES), O-tert-butyldimethylsilyl (O-TBDMS), O-tert-butyldiphenylsilyl (O-TBDPS), and O-triisopropylsilyl (O-TIPS) ethers of D-glucal to the corresponding C(6)-O-formates. |
| Doi | 10.1021/jo005540t |
| Pmid | 11430084 |
| Wosid | WOS:000166943800008 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |