Palladium-catalyzed allylation of malonic acid derivatives in heterogeneous systems containing ionic liquids
Vasil'ev, AA; Zlotin, SG
| HERO ID | 4936171 |
|---|---|
| In Press | No |
| Year | 2014 |
| Title | Palladium-catalyzed allylation of malonic acid derivatives in heterogeneous systems containing ionic liquids |
| Authors | Vasil'ev, AA; Zlotin, SG |
| Journal | Mendeleev Communications |
| Volume | 24 |
| Issue | 1 |
| Page Numbers | 23-25 |
| Abstract | Palladium-catalyzed potassium carbonate-assisted reaction between diethyl malonate and allyl acetate in the presence of 1,3-dialkylimidazolium ionic liquids (ILs) as solvents or phase transfer catalysts affords major monoallylation product, whereas in the presence of 1,2,3-trialkylimidazolium or quaternary ammonium/phosphonium ILs diallylation product is preferably formed. These procedures are extended to some other CH-acids and allylic acetates. |
| Doi | 10.1016/j.mencom.2013.12.007 |
| Wosid | WOS:000331163400007 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |