CuI/L-proline-catalyzed coupling reactions of aryl halides with activated methylene compounds

Xie, X; Cai, G; Ma, D

HERO ID

4923608

Reference Type

Journal Article

Year

2005

Language

English

PMID

16209512

HERO ID 4923608
In Press No
Year 2005
Title CuI/L-proline-catalyzed coupling reactions of aryl halides with activated methylene compounds
Authors Xie, X; Cai, G; Ma, D
Journal Organic Letters
Volume 7
Issue 21
Page Numbers 4693-4695
Abstract [reaction: see text] The arylation of ethyl acetoacetate, ethyl benzoyl acetate, and diethyl malonate under the catalysis of CuI/L-proline in DMSO proceeds smoothly at 40-50 degrees C in the presence of Cs2CO3 to provide the 2-aryl-1,3-dicarbonyl compounds in good yields. Both aryl iodides and aryl bromides are compatible with these reaction conditions.
Doi 10.1021/ol0518838
Pmid 16209512
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English