Activation energy of the two-proton phototautomerism in 7-azaindole dimer and its medium-dependence
Catalán, J
| HERO ID | 4868755 |
|---|---|
| In Press | No |
| Year | 2010 |
| Title | Activation energy of the two-proton phototautomerism in 7-azaindole dimer and its medium-dependence |
| Authors | Catalán, J |
| Journal | Journal of Physical Chemistry A |
| Volume | 114 |
| Issue | 18 |
| Page Numbers | 5666-5673 |
| Abstract | A photophysical analysis of 10(-4) M solutions of 7-azaindole in hydrocarbon solvents including 2-methylbutane, 3-methylpentane, ethylcyclohexane, decalin, and squalane revealed that the viability of the two-proton phototautomerism in its dimer is clearly medium-dependent. However, in all media studied, a small tunneling contribution in the photoinduced double proton transfer continues to exist at low temperatures. |
| Doi | 10.1021/jp911965s |
| Pmid | 20397681 |
| Wosid | WOS:000277280400007 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |