Two novel bimetallic transition metal-uranyl one-dimensional coordination polymers with manganese(II) and cobalt(II) incorporating bridging diglycolate (2,2'-oxydiacetate) ligands
Ridenour, JA; Pyrch, MM; Manning, ZJ; Bertke, JA; Cahill, CL
| HERO ID | 4259954 |
|---|---|
| In Press | No |
| Year | 2017 |
| Title | Two novel bimetallic transition metal-uranyl one-dimensional coordination polymers with manganese(II) and cobalt(II) incorporating bridging diglycolate (2,2'-oxydiacetate) ligands |
| Authors | Ridenour, JA; Pyrch, MM; Manning, ZJ; Bertke, JA; Cahill, CL |
| Volume | 73 |
| Issue | Pt 8 |
| Page Numbers | 588-592 |
| Abstract | The crystal structures of two new bimetallic uranyl-transition metal compounds with diglycolic acid [or 2-(carboxymethoxy)acetic acid] have been hydrothermally synthesized and structurally characterized via single-crystal X-ray diffraction. The compounds, namely catena-poly[[[tetraaquamanganese(II)]-μ-2,2'-oxydiacetato-[dioxidouranium(VI)]-μ-2,2'-oxydiacetato] dihydrate], {[MnU(C4H4O5)2O2(H2O)4]·2H2O}n, and catena-poly[[[tetraaquacobalt(II)]-μ-2,2'-oxydiacetato-[dioxidouranium(VI)]-μ-2,2'-oxydiacetato] dihydrate], {[CoU(C4H4O5)2O2(H2O)4]·2H2O}n, both crystallize in the triclinic space group P-1. These compounds form one-dimensional chains via alternating uranyl and transition metal building units. The chains then assemble into three-dimensional supramolecular networks through several hydrogen bonds between water molecules and diglycolate ligands. Luminescence measurements were conducted and no uranyl emission was observed in either compound. |
| Doi | 10.1107/S2053229617009263 |
| Pmid | 28776508 |
| Wosid | WOS:000407181100001 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Journal: Acta crystallographica. Section C, Structural chemistry ISSN: 2053-2296 |
| Is Public | Yes |
| Language Text | English |