A laser flash photolysis study of curcumin in dioxane-water mixtures
Ortica, F; Rodgers, MAJ
| HERO ID | 3684084 |
|---|---|
| In Press | No |
| Year | 2001 |
| Title | A laser flash photolysis study of curcumin in dioxane-water mixtures |
| Authors | Ortica, F; Rodgers, MAJ |
| Journal | Photochemistry and Photobiology |
| Volume | 74 |
| Issue | 6 |
| Page Numbers | 745-751 |
| Abstract | Curcumin [bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione] was studied by means of UV-VIS absorption spectroscopy and nanosecond laser flash photolysis in 1,4-dioxane-water mixtures in a series of dioxane-water volume ratios. The transient characteristics were found to be dependent on the amount of water. In pure dioxane the triplet state of the molecule in its enolic form was detected (lambda(max) = 720 nm, tau = 3.2 micros), whereas upon water addition, the diketo form was found to prevail, because of the perturbation of intramolecular H-bonded structure. This led to hydrogen abstraction from dioxane by curcumin triplet state and the formation of the corresponding ketyl radical (lambda(max) = 490 nm, tau approximately 10 micros). Laser flash photolysis measurements, carried out in solvents of different polarity and proticity (benzene, cyclohexane and various alcohols), allowed the transient assignments to be confirmed, supporting our interpretation. |
| Doi | 10.1562/0031-8655(2001)074<0745:alfpso>2.0.co;2 |
| Pmid | 11783928 |
| Wosid | WOS:000172863800001 |
| Url | https://www.proquest.com/scholarly-journals/laser-flash-photoysis-study-curcumin-dioxane/docview/237203225/se-2?accountid=171501 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |
| Keyword | Biology; Dioxanes; Solvents; 1,4-dioxane; Curcumin; Hydrogen Bonding; Photolysis; Spectrophotometry; Spectrophotometry, Ultraviolet; Photochemistry; Curcumin -- radiation effects; Curcumin -- chemistry |
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