The host materials containing carbazole and oxadiazole fragment for red triplet emitter in organic light-emitting diodes

Guan, Min; Chen, Z; Bian, Z; Liu, Z; Gong, Z; Baik, W; Lee, H; Huang, C

HERO ID

3576155

Reference Type

Journal Article

Year

2006

HERO ID 3576155
In Press No
Year 2006
Title The host materials containing carbazole and oxadiazole fragment for red triplet emitter in organic light-emitting diodes
Authors Guan, Min; Chen, Z; Bian, Z; Liu, Z; Gong, Z; Baik, W; Lee, H; Huang, C
Journal Organic Electronics
Volume 7
Issue 5
Page Numbers 330-336
Abstract Three new oxadiazole substituted carbazole derivatives 9-{4-[5-(4-tert-butylphenyl)-[1,3,4] oxadiazol-2-yl]-benzyl}-9 H-carbazole (t-CmOxa), 9-[4-5-phenyl-[1,3,4]oxadiazol-2-yl-benzyl]-9H-carbazole (p-CmOxa) and 9-[4-5-biphenyl-[1,3,4] oxadiazol-2-yl-benzyl]-9H-carbazole (d-CmOxa) were successfully synthesized and characterized by spectroscopy (NMR, UV-vis, mass spectrum and photoluminescence) and cyclic voltammetry measurements. Employing t-CmOxa as a host and Ir(DBQ)(2)(acac) (DBQ = dibenzo[f,h]quinoxaline, acac = acetylacetonate) as the dopant emitter, OLEDs with structures of ITO/NPB(30 nm)/Ir(DBQ)(2)(acac): t-CmOxa (30 nm, x%)/Alq(3)(30 nm)/Mg-0.9:Ag-0.1 were fabricated without using BCP as the hole blocking layer. Red emission was obtained with CIE coordinates (x = 0.66, and y = 0. 34) at 5 V and a very high external electrolunimescent (EL) quantum efficiency of 9.5 +/- 0.1%, and an energy conversion efficiency of 9.9 +/- 0.1 lm/W were achieved for the device when the doping concentration x is equal to 4%. (C) 2006 Elsevier B.V. All rights reserved.
Doi 10.1016/j.orgel.2006.04.006
Wosid WOS:000241956800013
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword oxadiazole; carbazole; OLED; red; host material