Reduction of the 3,4,9,10-perylenediimides and the formation of eletrodeposited films based on their radical anions
Zhu, YY; Gu, SXi
| HERO ID | 3576038 |
|---|---|
| In Press | No |
| Year | 2014 |
| Title | Reduction of the 3,4,9,10-perylenediimides and the formation of eletrodeposited films based on their radical anions |
| Authors | Zhu, YY; Gu, SXi |
| Journal | Materials Research Express |
| Volume | 1 |
| Issue | 3 |
| Abstract | The reduction of the two 3,4,9,10-perylene diimide (PDI) derivatives in the mixture of hydrazine hydrate and N, N-dimethylformamide was investigated by the UV-vis absorption spectra, fluorescence spectra (FL) and electron spin resonance spectroscopy (ESR). The time dependence of the PDI content, as well as the structure of PDI aggregates were also investigated and discussed. Combining the electro-migration behavior of PDI- with the molecular self-assembly properties, the films of two PDI derivatives (PDI-32 and PDI-123) were successfully fabricated via anode electro-deposition (AED). The difference of aggregation state between the two PDI films was studied by UV-vis absorption spectra, XRD and SEM. Based on these, the formation mechanism of PDI films was also deduced. |
| Doi | 10.1088/2053-1591/1/3/035102 |
| Wosid | WOS:000209665200056 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Journal:MATERIALS RESEARCH EXPRESS 2053-1591 |
| Is Public | Yes |
| Keyword | perylenediimides; radical anion; electrodeposition; aggregation state |