Retention capacities of immiscible chemicals in unsaturated soils

Guigard, SE; Stiver, WH; Zytner, RG

HERO ID

3559605

Reference Type

Journal Article

Year

1996

Language

English

HERO ID 3559605
In Press No
Year 1996
Title Retention capacities of immiscible chemicals in unsaturated soils
Authors Guigard, SE; Stiver, WH; Zytner, RG
Journal Water, Air, and Soil Pollution
Volume 89
Issue 3-4
Page Numbers 277-289
Abstract Retention capacities were measured in the laboratory for n-hexane and tetrachloroethylene (PCE) in three soils at varying soil water contents. Two experimental techniques were used; 1) saturation/drainage experiments where the soil columns were saturated with the chemical and allowed to drain freely for 24 h, and 2) spill simulations where a known amount of chemical was spilled on the surface of the soil column and allowed to infiltrate for one hour. Results show that the retention capacities on a volume basis were independent of chemical type. However, the retention capacities did decrease with decreasing porosity and increasing soil water content. The decrease of retention capacity with respect to soil water content was significant, with the decreases ranging from 38% to 94%. The implication of this decrease is rapid chemical penetration into the subsurface. Retention capacities obtained from spill simulations were consistently lower than those obtained by the saturation/drainage experiments due to hysteresis.
Doi 10.1007/BF00171637
Wosid WOS:A1996UT88100005
Is Certified Translation No
Dupe Override No
Comments Scopus URL: https://www.scopus.com/inward/record.uri?eid=2-s2.0-0029663144&doi=10.1007%2fBF00171637&partnerID=40&md5=90d73ca756eea56964d9c1928d350eb7
Is Public Yes
Language Text English
Keyword n-hexane; tetrachloroethylene; unsaturated soil; retention capacity; soil water content