Novel non-aqueous Fe(III)/Fe(II) redox couple for the catalytic oxidation of hydrogen sulfide to sulfur by air
Hua, G; Zhang, Q; Mcmanus, D; Slawin, AM; Woollins, JD
| HERO ID | 3539825 |
|---|---|
| In Press | No |
| Year | 2006 |
| Title | Novel non-aqueous Fe(III)/Fe(II) redox couple for the catalytic oxidation of hydrogen sulfide to sulfur by air |
| Authors | Hua, G; Zhang, Q; Mcmanus, D; Slawin, AM; Woollins, JD |
| Journal | Dalton Transactions |
| Issue | 9 |
| Page Numbers | 1147-1156 |
| Abstract | A series of Fe(III) salts and organic solvents have been screened to develop novel non-aqueous catalysts for the conversion of H2S to sulfur. FeCl3/95% N-methylpyrrolidinone/5% H2O was found to be a most efficient non-aqueous system. The process chemistry, the proposed mechanism of catalytic oxidation of H2S, and the electrochemistry are discussed. |
| Doi | 10.1039/b513384j |
| Pmid | 16482350 |
| Wosid | WOS:000235989700005 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |