Synthesis and characterisation of pore-expanded mesoporous silica materials

Ma, J; Liu, Q; Chen, D; Wen, S; Wang, T

HERO ID

2906102

Reference Type

Journal Article

Year

2015

HERO ID 2906102
In Press No
Year 2015
Title Synthesis and characterisation of pore-expanded mesoporous silica materials
Authors Ma, J; Liu, Q; Chen, D; Wen, S; Wang, T
Journal Micro and Nano Letters
Volume 10
Issue 2
Page Numbers 140-144
Abstract Mesoporous silicas are synthesised using 1,3,5-trimethylbenzene (TMB) and heptanes as pore expanders. Small-angle X-ray diffraction and N-2 adsorption-desorption isotherms at 77 K were used to characterise the pore structure of the prepared materials. The porosity increased with the added TMB amount for samples using TMB as a pore expander and a total pore value of 2.48 cm(3)/g was obtained, representing an increase by a factor of 2.4 as compared with mesoporous silica without TMB addition. For samples with heptanes as a pore expander, the pore volume increased with synthesis temperature. The mesoporous silica synthesised at 52 degrees C had a total pore volume of 2.38 cm(3)/g.
Doi 10.1049/mnl.2014.0413
Wosid WOS:000350483000019
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword silicon compounds; porosity; adsorption; desorption; X-ray diffraction; mesoporous materials; pore-expanded mesoporous silica materials; 1; 3; 5-trimethylbenzene; heptanes; small-angle X-ray diffraction; N-2 adsorption-desorption isotherms; porosity; temperature 77 K; temperature 52 degC; SiO2