Inhibition effect of Na⁺ and Ca²⁺ on the bioaccumulation of perfluoroalkyl substances by Daphnia magna in the presence of protein

Xia, X; Rabearisoa, AH; Dai, Z; Jiang, X; Zhao, P; Wang, H

HERO ID

2851057

Reference Type

Journal Article

Year

2015

Language

English

PMID

25477240

HERO ID 2851057
In Press No
Year 2015
Title Inhibition effect of Na⁺ and Ca²⁺ on the bioaccumulation of perfluoroalkyl substances by Daphnia magna in the presence of protein
Authors Xia, X; Rabearisoa, AH; Dai, Z; Jiang, X; Zhao, P; Wang, H
Journal Environmental Toxicology and Chemistry
Volume 34
Issue 2
Page Numbers 429-436
Abstract The authors investigated the individual effects of Ca(2+) and Na(+) on the bioaccumulation of 6 types of perfluoroalkyl substances (PFASs), including perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), perfluorodecanoic acid (PFDA), perfluoroundecanoic acid (PFUnA), and perfluorododecanoic acid (PFDoA), by Daphnia magna in water with 10 mg L(-1) bovine albumin or soy peptone. The bioaccumulation factors of PFASs by D. magna decreased linearly with the increase of Ca(2+) and Na(+) concentrations. The inhibition effect of Ca(2+) was stronger than that of Na(+), and the decreasing percentages of the body burden of PFASs in D. magna caused by the increment of 1 mmol L(-1) Ca(2+) and 1 mmol L(-1) Na(+) were 41% to approximately 48% and 2% to approximately 5%, respectively, in the presence of soy peptone. The partition coefficients (Kp) of PFASs between protein and water increased with rising Ca(2+) and Na(+) concentrations. The elevated Kp values led to the reduced concentrations of freely dissolved PFASs. This resulted in a decrease of PFAS bioaccumulation in D. magna, and the body burden of each PFAS was positively correlated with its freely dissolved concentration in water. The present study suggests that cations should be considered in the assessment of bioavailability and risk of PFASs in natural waters containing proteinaceous compounds.
Doi 10.1002/etc.2823
Pmid 25477240
Wosid WOS:000348994200026
Is Certified Translation No
Dupe Override No
Comments Potential Matches To This Reference: 2851057 6390931 Potential Matches To This Reference: 2851057 6390931Scopus URL: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84922591760&doi=10.1002%2fetc.2823&partnerID=40&md5=23c965abcb2c4d7b011e018993ff98d6
Is Public Yes
Language Text English
Keyword Bioavailability; Protein; Perfluoroalkyl substances (PFASs); Cations; Dissolved organic matter (DOM)
Is Peer Review Yes
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