An rht-type metal-organic framework constructed from an unsymmetrical ligand exhibiting high hydrogen uptake capability
Li, J; Li, PeiZ; Li, QiuYan; Cao, Y; Lu, Han; Wu, Hui; Li, Fei; Shi, Y; Wang, XJun; Zhao, Y
| HERO ID | 2841889 |
|---|---|
| In Press | No |
| Year | 2014 |
| Title | An rht-type metal-organic framework constructed from an unsymmetrical ligand exhibiting high hydrogen uptake capability |
| Authors | Li, J; Li, PeiZ; Li, QiuYan; Cao, Y; Lu, Han; Wu, Hui; Li, Fei; Shi, Y; Wang, XJun; Zhao, Y |
| Journal | RSC Advances |
| Volume | 4 |
| Issue | 96 |
| Page Numbers | 53975-53980 |
| Abstract | An unsymmetrical hexatopic carboxylate acid (H6-1) ligand containing one acrylamide unit and two triazole groups was designed and synthesized, and then used to construct a metal-organic framework (MOF Cu-ABTA) via a solvothermal reaction with Cu(NO3)(2). A powder X-ray diffraction investigation indicated that the MOF Cu-ABTA possesses a (3,24)-connected rht-network, as does our previously reported MOF NTU-105 with three triazole groups. The gas sorption measurements revealed that Cu-ABTA shows high porosity and a very high H-2-uptake capability with a strong H-2 binding affinity as demonstrated by the enhanced isosteric heat of adsorption, which make it a highly promising candidate for clean energy storage. |
| Doi | 10.1039/c4ra07101h |
| Wosid | WOS:000344468800077 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |