Binuclear complex [Cu(bappz)(mu-NC)Ni(CN)(3)]center dot H2O (bappz=1,4-bis(3-aminopropyl)piperazine)
Smekal, Z; Adams, H
| HERO ID | 2841694 |
|---|---|
| In Press | No |
| Year | 2014 |
| Title | Binuclear complex [Cu(bappz)(mu-NC)Ni(CN)(3)]center dot H2O (bappz=1,4-bis(3-aminopropyl)piperazine) |
| Authors | Smekal, Z; Adams, H |
| Journal | Journal of Structural Chemistry |
| Volume | 55 |
| Issue | 6 |
| Page Numbers | 1111-1115 |
| Abstract | The novel bimetallic compound [Cu(bappz)(mu-NC)Ni(CN)(3)]center dot H2O (bappz = 1,4-bis(3-aminopropyl) piperazine) is prepared by the reaction of Cu(NO3)center dot 3H(2)O, bappz, and K-2[Ni(CN)(4)] in water. The complex is characterized by IR spectroscopy and single crystal X-ray diffraction. The neutral [Cu(bappz)(mu-NC)Ni(CN)(3)] complex assumes a cyanide-bridged binuclear structure in which the nickel(II) ion is four-coordinated by carbon atoms from four cyano groups (one of them forms a bridge) in a square planar arrangement, whereas the copper(II) ion is five-coordinated by four bappz nitrogen and one cyanide nitrogen atoms in a distorted square-pyramidal geometry. |
| Doi | 10.1134/S0022476614060171 |
| Wosid | WOS:000348401200017 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | copper(II) complexes; tetracyanonickelates(II); cyano-bridged complexes; X-ray structure analysis |