Gas Adsorption, Magnetism, and Single-Crystal to Single-Crystal Transformation Studies of a Three-Dimensional Mn(II) Porous Coordination Polymer
Agarwal, RA; Mukherjee, S; Carolina Sanudo, E; Ghosh, SK; Bharadwaj, PK
| HERO ID | 2841014 |
|---|---|
| In Press | No |
| Year | 2014 |
| Title | Gas Adsorption, Magnetism, and Single-Crystal to Single-Crystal Transformation Studies of a Three-Dimensional Mn(II) Porous Coordination Polymer |
| Authors | Agarwal, RA; Mukherjee, S; Carolina Sanudo, E; Ghosh, SK; Bharadwaj, PK |
| Journal | Crystal Growth & Design |
| Volume | 14 |
| Issue | 11 |
| Page Numbers | 5585-5592 |
| Abstract | A porous coordination polymer {[Mn2(DBIBA)3]NO3.3DMF.4H2O}n (1) [DBIBAH = 3,5-di(1H-benzo[d]imidazol-1-yl)benzoic acid] has been synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction. The following four new coordination polymers {[Mn2(DBIBA)3].ClO4.DMF.H2O}n (2), {[Mn2(DBIBA)3].Cl.DMF.8H2O}n (3), {[Mn2(DBIBA)3].NO3.CH3OH.5H2O}n (4) and {[Mn2(DBIBA)3].NO3.3CH3COCH3.7H2O}n (5) have been synthesized from 1 via anion/solvent exchange protocols in a single-crystal to single-crystal fashion at room temperature. Gas sorption studies for desolvated compounds 1, 2, and 3 show that CO2 uptake capacity is entirely dependent upon the size of the anion present in the framework. Complex 1 also exhibits antiferromagnetic properties below 17 K, confirmed through magnetic susceptibility measurements. |
| Doi | 10.1021/c9500833s |
| Wosid | WOS:000344516800032 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |