Chemical and morphological characteristics of solid metal-bearing phases deposited in snow and stream sediment as indicators of their origin

Miler, M; Gosar, M

HERO ID

2535068

Reference Type

Journal Article

Year

2014

Language

English

PMID

25233920

HERO ID 2535068
In Press No
Year 2014
Title Chemical and morphological characteristics of solid metal-bearing phases deposited in snow and stream sediment as indicators of their origin
Authors Miler, M; Gosar, M
Journal Environmental Science and Pollution Research
Volume 22
Issue 3
Page Numbers 1906-1918
Abstract Detailed scanning electron microscopy/energy dispersive spectroscopy of metal-bearing particles in snow deposits and stream sediment from a steelworks area was performed. Identified metal-bearing phases were apportioned according to their chemical and morphological characteristics to anthropogenic phases and secondary weathering products. Anthropogenic metal-bearing phases are the most abundant in both media and are represented by various irregular ferrous oxides, ferrous alloys, spherical ferrous oxides, and ferrous silicates with variable contents of Cr, Mn, Ni, V, W, and Mo. Secondary weathering products are Al silicates, Fe oxy-hydroxides, and Fe oxy-hydroxy sulfates with minor contents of transition metals, resulting from weathering of anthropogenic phases and Pb-Zn ore minerals from a closed Pb-Zn mine located upstream from the study area. Comparison of anthropogenic metal-bearing phases in both media showed agreement in their compositions and morphologies and indicated their sources are high-temperature processes in steel production. It also showed that spherical metal-bearing phases were transported by the same transport medium, which is the atmosphere, while other phases were transported into stream sediment mostly by other pathways, such as precipitation runoff over contaminated surfaces.
Doi 10.1007/s11356-014-3589-x
Pmid 25233920
Wosid WOS:000348917400040
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English
Keyword Snow deposits; Stream sediment; Metal-bearing phases; SEM/EDS; Source identification