Determination of emerging and priority industrial pollutants in surface water and wastewater by liquid chromatography-negative electrospray ionization tandem mass spectrometry

Martín, J; Camacho-Muñoz, D; Santos, JL; Aparicio, I; Alonso, E

HERO ID

2343696

Reference Type

Journal Article

Year

2014

Language

English

PMID

24633504

HERO ID 2343696
In Press No
Year 2014
Title Determination of emerging and priority industrial pollutants in surface water and wastewater by liquid chromatography-negative electrospray ionization tandem mass spectrometry
Authors Martín, J; Camacho-Muñoz, D; Santos, JL; Aparicio, I; Alonso, E
Journal Analytical and Bioanalytical Chemistry
Volume 406
Issue 15
Page Numbers 3709-3716
Abstract A method for the simultaneous determination of six perfluoroalkyl compounds (perfluorooctanesulfonic acid (PFOS) and five perfluoroalkyl carboxylic acids), five phenolic compounds (nonylphenol (NP), bisphenol A (BPA), and methyl-, ethyl- and propylparabens), and the brominated flame retardant hexabromocyclododecane (HBCDD) in surface water and effluent wastewater has been developed. The selected pollutants include eight of the industrial pollutants (PFOS and derivatives, NP, and HBCDD) that could be regulated in surface water according to an European Union Directive proposal and four compounds of great concern because their estrogenicity (BPA and parabens). The method is based on solid-phase extraction and determination by high-performance liquid chromatography-triple quadrupole mass spectrometry in negative electrospray ionization mode. Method quantitation limits of NP, PFOS and derivatives, and HBCDD allow its application for routinely control of surface water according to the EU proposal of directive.
Doi 10.1007/s00216-014-7689-8
Pmid 24633504
Wosid WOS:000336393900020
Url https://www.scopus.com/inward/record.uri?eid=2-s2.0-84901642025&doi=10.1007%2fs00216-014-7689-8&partnerID=40&md5=60cf032220ae7241fe833c720c3817d1
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English
Keyword Industrial pollutants; Surface water; Effluent wastewater; High-performance liquid chromatography; Negative ion mass spectrometry