Synthesis, crystal structure, and spectral properties of tris-[4,4,5,5,6,6,6-heptafluoro-1-(1-methyl-1H-pyrazol-4-yl)-1,3-hexanedionato](diethanolo)gadolinium(III)
Taidakov, IV; Vitukhnovskii, AG; Nefedov, SE
| HERO ID | 2289346 |
|---|---|
| In Press | No |
| Year | 2013 |
| Title | Synthesis, crystal structure, and spectral properties of tris-[4,4,5,5,6,6,6-heptafluoro-1-(1-methyl-1H-pyrazol-4-yl)-1,3-hexanedionato](diethanolo)gadolinium(III) |
| Authors | Taidakov, IV; Vitukhnovskii, AG; Nefedov, SE |
| Journal | Russian Journal of Inorganic Chemistry |
| Volume | 58 |
| Issue | 7 |
| Page Numbers | 783-787 |
| Abstract | Reaction of Gd(NO3)(3) center dot 6H(2)O with 4,4,5,5,6,6,6-heptafluoro-1-(1-methyl-1H-pyrazol-4-yl)-1,3-hexanedione in aqueous ethanol solution in the presence of NaOH at ambient temperature was found to give rise to complex GdL3[O(H)Et](2) in 64% yield. The prepared complex was characterized by X-ray crystallography, its luminescent properties were studied, and the energy of ligand triplet level was determined experimentally. |
| Doi | 10.1134/S0036023613070218 |
| Wosid | WOS:000322390100008 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |