Size-controlled synthesis of highly water-soluble silver nanocrystals

Hu, Y; Ge, J; Lim, D; Zhang, T; Yin, Y

HERO ID

224894

Reference Type

Journal Article

Year

2008

HERO ID 224894
In Press No
Year 2008
Title Size-controlled synthesis of highly water-soluble silver nanocrystals
Authors Hu, Y; Ge, J; Lim, D; Zhang, T; Yin, Y
Journal Journal of Solid State Chemistry
Volume 181
Issue 7
Page Numbers 1524-1529
Abstract We describe a modified polyol process for the synthesis of silver nanocrystals with uniform sizes ranging from several nanometers to ∼20 nm. The use of polyacrylic acid, in place of polyvinylpyrrolidone in the conventional polyol process, significantly limits the growth of silver nanocrystals, prevents the interparticle aggregation and fusion, and leads to a uniform population of samples with high water solubility. The size of nanocrystals can be conveniently tuned by controlling the reaction time, the concentration and chain length of the polymeric surfactants, and the reaction temperature. Uniform silver nanocrystals within sizes below 20 nm are preferred candidates over larger particles for applications where high density of optical absorption is required, for example, for photothermal conversion in cancer therapy.
Doi 10.1016/j.jssc.2008.02.028
Is Certified Translation No
Dupe Override No
Is Public Yes
Is Qa No