Influence of variable species composition on the saccharification of AFEX (TM) pretreated biomass from unmanaged fields in comparison to corn stover

Garlock, RJ; Bals, B; Jasrotia, P; Balan, V; Dale, BE

HERO ID

2039916

Reference Type

Journal Article

Year

2012

HERO ID 2039916
In Press No
Year 2012
Title Influence of variable species composition on the saccharification of AFEX (TM) pretreated biomass from unmanaged fields in comparison to corn stover
Authors Garlock, RJ; Bals, B; Jasrotia, P; Balan, V; Dale, BE
Journal Biomass and Bioenergy
Volume 37
Page Numbers 49-59
Abstract From the perspective of the biorefinery, the inherent heterogeneity of mixed-species feedstocks increases the apparent risk associated with their use due to the difficulty in predicting processing characteristics, potential yields and digestibility. These materials often contain species from different botanical classifications, which could affect pretreatment efficiency and Saccharification yields. For this study, we evaluated the impact of ammonia fiber expansion (AFEX (TM)(1)) pretreatment conditions on hydrolysis sugar yields for five early successional old-field treatment replicates, each comprised of a different mixture of annual forb and grass species. Yields from these samples were also compared to a late successional old field sample and to corn stover that had been pretreated at the same conditions. Relatively high sugar yields were obtained for four of the five early successional feedstocks when pretreated at the same conditions: 2.0 g NH3:g DM; 0.5 g H2O:g DM; 100 degrees C; 30 min. It was found that glucan digestibility was strongly inversely correlated to the total lignin content; however this was not true of the xylan digestibility. The mixed-species feedstocks that had a higher grass content tended to also have a higher structural sugar content and were more digestible than forb-dominated feedstocks, thereby resulting in higher saccharification yields. Also, the grass-dominated mixed-species feedstocks were as digestible as corn stover (similar to 80% total sugar yields). However, due to its higher structural sugar content, corn stover had higher total glucose and xylose yields (580 g/kg biomass) compared to the mixed-species feedstocks, which ranged from 290 to 470 g/kg biomass. (C) 2011 Elsevier Ltd. All rights reserved.
Doi 10.1016/j.biombioe.2011.12.036
Wosid WOS:000300921200007
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword Ammonia fiber expansion (AFEX (TM)); Botanical classification; Cellulosic biofuel; Enzymatic hydrolysis; Mixed-species feedstock; Old field