Layered TiO2: PVK nano-composite thin films for photovoltaic applications. TiO2: PVK nano-composite thin films

Kaune, G; Wang, W; Metwalli, E; Ruderer, M; Rossner, R; Roth, SV; Müller-Buschbaum, P

HERO ID

1941322

Reference Type

Journal Article

Year

2008

Language

English

PMID

18414788

HERO ID 1941322
In Press No
Year 2008
Title Layered TiO2: PVK nano-composite thin films for photovoltaic applications. TiO2: PVK nano-composite thin films
Authors Kaune, G; Wang, W; Metwalli, E; Ruderer, M; Rossner, R; Roth, SV; Müller-Buschbaum, P
Journal European Physical Journal E. Soft Matter and Biological Physics
Volume 26
Issue 1-2
Page Numbers 73-79
Abstract The influence of the solvent used for spin-coating on the homogeneity of poly(N-vinylcarbazole) (PVK) films is investigated. Homogenous films are obtained only by the use of toluene, solution in tetrahydrofuran (THF) and chloroform results in radially oriented inhomogeneities and films prepared by use of N-methylpyrrolidone and dimethylacetamide show particle formation during spin-coating. Layered nano-composite thin films are prepared by spin-coating a PVK film on top of a nano-structured titanium dioxide ( TiO2) layer. The TiO2 thin films are prepared by a sol-gel process using an amphiphilic copolymer as structure-directing agent. Structural characterisation of the TiO2 :PVK nano-composite films is done by field emission scanning electron microscopy (FESEM) and grazing-incidence small-angle scattering (GISAXS). Bare TiO2 films are probed for comparison. Light is basically only absorbed in the ultraviolet regime and absorption slightly increases upon addition of PVK, which makes the layered TiO2 :PVK nano-composite thin films good candidates for UV photovoltaic devices. Furthermore, absorption remains stable over a period of several days.
Doi 10.1140/epje/i2007-10292-2
Pmid 18414788
Wosid WOS:000256329100009
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English