Synthesis and Characterization of New Type Soluble Porphyrazine Containing 1-Bromo-3-Methylbutan Group and Investigation of Its Complexes
Erdogmus, Ali; Karaoglan, GK; Avciata, U; Guel, A
| HERO ID | 1840353 |
|---|---|
| In Press | No |
| Year | 2009 |
| Title | Synthesis and Characterization of New Type Soluble Porphyrazine Containing 1-Bromo-3-Methylbutan Group and Investigation of Its Complexes |
| Authors | Erdogmus, Ali; Karaoglan, GK; Avciata, U; Guel, A |
| Page Numbers | 375-381 |
| Abstract | Bis(3-methylbutantio) maleonitril has been obtained from the reaction of disodium salt, 1-bromo-3 methylbutan in acetone under nitrogen for 11 hours. MgPz has been synthesized through the cyclotetramerization reaction of magnesium and n-butanol with bis(3-methylbutantio) maleonitril. The metal free pophyrazine derivative was obtained by its treatment with trifluroacetic acid and further reaction of this product with cobalt(H) acetate, nickel(II) acetate and zinc(II) acetate led to the metal porphyrazine (MPz, M = Co, Ni ve Zn). These new compounds have been investigated and characterized by UV, FT-IR, H-1 NMR, GC-MS and elemental analysis methods. |
| Doi | 10.1007/978-1-4020-6955-0_44 |
| Wosid | WOS:000262502000044 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Source: Web of Science WOS:000262502000044 Journal:Innovations in Chemical Biology |
| Is Public | Yes |
| Keyword | Magnesium; nickel; pigment; phythalocyanines; porphyrazine; spectroscopy; synthesis |