Catalytic hydrodechlorination of 2,4-dichlorophenol over nanoscale Pd/Fe: reaction pathway and some experimental parameters
Wei, J; Xu, X; Liu, Y; Wang, D
HERO ID
178193
Reference Type
Journal Article
Year
2006
Language
English
PMID
| HERO ID | 178193 |
|---|---|
| In Press | No |
| Year | 2006 |
| Title | Catalytic hydrodechlorination of 2,4-dichlorophenol over nanoscale Pd/Fe: reaction pathway and some experimental parameters |
| Authors | Wei, J; Xu, X; Liu, Y; Wang, D |
| Journal | Water Research |
| Volume | 40 |
| Issue | 2 |
| Page Numbers | 348-354 |
| Abstract | Nanoscale Pd/Fe bimetallic particles were synthesized and used to hydrodechlorinate 2,4-dichlorophenol. 2,4-dichlorophenol was transformed to phenol with a small amount of 2-chlorophenol and 4-chlorophenol produced. The reaction pathway and reaction rate constants for each step have been determined. The effects of various Pd bulk loadings in the bi-metals, temperatures and pH conditions on the hydrodechlorination of 2,4-dichlorophenol were examined. The results showed that higher Pd bulk loadings, higher temperatures and weak acid conditions are beneficial to the catalytic dechlorination of 2,4-dichlorophenol. |
| Doi | 10.1016/j.watres.2005.10.017 |
| Pmid | 16336988 |
| Wosid | WOS:000235088400019 |
| Url | https://www.scopus.com/inward/record.uri?eid=2-s2.0-29644442099&doi=10.1016%2fj.watres.2005.10.017&partnerID=40&md5=c00c271476493932914b41eefa8bf166 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |
| Keyword | Anthelmintics/ chemistry; Catalysis; Chlorophenols/ chemistry; Hydrogen-Ion Concentration; Iron/chemistry; Lead/chemistry; Nanostructures; Temperature; Water Purification/ methods |
| Is Qa | No |