Application of heterogeneous adsorbents in removal of dimethyl phthalate: Equilibrium and heat

Wu, Jun; Xu, Z; Zhang, W; Lv, Lu; Pan, B; Nie, G; Li, M; Du, Q

HERO ID

1599825

Reference Type

Journal Article

Year

2010

HERO ID 1599825
In Press No
Year 2010
Title Application of heterogeneous adsorbents in removal of dimethyl phthalate: Equilibrium and heat
Authors Wu, Jun; Xu, Z; Zhang, W; Lv, Lu; Pan, B; Nie, G; Li, M; Du, Q
Journal AIChE Journal
Volume 56
Issue 10 (Oct 2010)
Page Numbers 2699.
Abstract Aminated resin (NDA-101) and oxidized resin (NDA-702) were synthesized to remove Dimethyl phthalate (DMP) from the contaminated water. The equilibrium and heat properties in the course of adsorption process were examined and compared with two commercial heterogeneous adsorbents, namely an acrylic ester resin (Amberlite XAD-7) and a coal-based granular activated carbon (AC-750). The associated equilibrium isotherms can be well fitted by Freundlich equation and the adsorption capacities for DMP followed the order: NDA-702 NDA-101 AC-750 XAD-7. The surface of XAD-7 was demonstrated to be relatively homogeneous through surface energy heterogeneity analysis, offering the sole hydrogen bonding interaction. Contrarily, heterogeneous surface of oxidized resins NDA-702 and the aminated resins NDA-101 exhibited a promising adsorption capacity and affinity toward DMP probably derived by multiple hydrogen bonding, ... stacking, and micropore filling interactions. (ProQuest: ... denotes formulae/symbols omitted.)
Doi 10.1002/aic.12175
Wosid WOS:000282288400019
Is Certified Translation No
Dupe Override No
Comments Source: Web of Science WOS:000282288400019
Is Public Yes
Keyword Esters; Capacity; Activated carbon; phthalates; Bonding; Adsorption; Heat; Resins; water pollution; Heterogeneity; Hydrogen; Adsorbents; Equilibrium