Simple inorganic complexes but intricate hydrogen bonding networks: Synthesis and crystal structures of [M-II(opda)(2)(NO3)(2)] (M = Zn and Cd; opda = orthophenylenediamine)
Supriya, S
| HERO ID | 1569214 |
|---|---|
| In Press | No |
| Year | 2009 |
| Title | Simple inorganic complexes but intricate hydrogen bonding networks: Synthesis and crystal structures of [M-II(opda)(2)(NO3)(2)] (M = Zn and Cd; opda = orthophenylenediamine) |
| Authors | Supriya, S |
| Journal | Proceedings of the Indian Academy of Sciences - Chemical sciences |
| Volume | 121 |
| Issue | 2 |
| Page Numbers | 137-143 |
| Abstract | The compounds [Zn-II{C6H4(NH2)(2)}(2)(NO3)(2)], (1) and [Cd-II{C6H4(NH2)(2)}(2)(NO3)(2)] (2) have been prepared (C6H4(NH2)(2) = orthophenylenediammine = opda) and characterized by routine spectroscopic methods and single crystal X-ray diffraction analysis. Compound 1 crystallizes in orthorhombic space group Pcab, where as compound 2 crystallizes in monoclinic space P2(1)/n. In the crystal structure of 1 an extended hydrogen bonding network is formed involving zinc coordinated amines and nitrato ligands. The compound 2 consists of molecules in which the cadmium ion is eight coordinated, with. two bidentate nitrate groups and two bidentate opda ligands. The geometry around the cadmium described as a distorted dodecahedron. The crystal structure of 2 shows an intricate hydrogen bonding network, formed by amine and nitro groups coordinated to cadmium. |
| Doi | 10.1007/s12039-009-0015-x |
| Wosid | WOS:000268244000003 |
| Url | <Go to ISI>://WOS:000268244000003 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Source: Web of Science WOS:000268244000003 |
| Is Public | Yes |
| Keyword | Orthophenylenediamine; metal complexes; crystal structures; intricate hydrogen bonding networks |