An influence of thermal treatment conditions of hydrotalcite-like materials on their catalytic activity in the process of N2O decomposition

Chmielarz, L; Rutkowska, M; Kustrowski, P; Drozdek, M; Piwowarska, Z; Dudek, B; Dziembaj, R; Michalik, M

HERO ID

1532617

Reference Type

Journal Article

Year

2011

HERO ID 1532617
In Press No
Year 2011
Title An influence of thermal treatment conditions of hydrotalcite-like materials on their catalytic activity in the process of N2O decomposition
Authors Chmielarz, L; Rutkowska, M; Kustrowski, P; Drozdek, M; Piwowarska, Z; Dudek, B; Dziembaj, R; Michalik, M
Journal Journal of Thermal Analysis and Calorimetry
Volume 105
Issue 1
Page Numbers 161-170
Abstract Hydrotalcite-like materials containing apart from magnesium and aluminum also copper, cobalt, nickel, and iron were prepared by a co-precipitation method. Thermal transformations of hydrotalcite-like materials were studied by thermal analysis methods as well as XRD, UV-vis-DRS, and XPS measurements of the samples calcined at various temperatures (600, 700, and 800 A degrees C). Calcined hydrotalcites, especially those containing cobalt and copper, were found to be active and selective catalysts of N2O decomposition. It was shown that an increase in the calcination temperature significantly activated the Co-containing catalysts. Promotion of the samples with potassium resulted in activation of the hydrotalcite-based catalysts.
Doi 10.1007/s10973-011-1284-4
Wosid WOS:000291747100021
Is Certified Translation No
Dupe Override No
Comments Source: Web of Science WOS:000291747100021
Is Public Yes
Keyword Hydrotalcites; Mixed metal oxides; Thermal analysis; Catalysis; N2O decomposition