Anthracene appended coumarin derivative as a Cr(III) selective turn-on fluorescent probe for living cell imaging: a green approach towards speciation studies

Guha, S; Lohar, S; Banerjee, A; Sahana, A; Mukhopadhyay, SK; Sanmartin Matalobos, J; Das, D

HERO ID

1447378

Reference Type

Journal Article

Year

2012

HERO ID 1447378
In Press No
Year 2012
Title Anthracene appended coumarin derivative as a Cr(III) selective turn-on fluorescent probe for living cell imaging: a green approach towards speciation studies
Authors Guha, S; Lohar, S; Banerjee, A; Sahana, A; Mukhopadhyay, SK; Sanmartin Matalobos, J; Das, D
Journal Analytical Methods
Volume 4
Issue 10
Page Numbers 3163-3168
Abstract A facile one step reaction between 6-aminocoumarin and anthracene-9-carboxaldehyde has resulted in a novel fluorescent probe, 6-((anthracen-9-yl) methyleneamino)-2H-chromen-2-one (AC) which is capable of selectively detecting intracellular Cr3+ in contaminated living cells under a fluorescence microscope. The binding of AC with Cr3+ is well characterized by different spectroscopic techniques. The binding constant values in CH3CN-water (9 : 1, v/v) and methanol-water (9 : 1, v/v) solutions have been estimated to be 1.1 x 10(5) and 3.1 x 10(5) respectively using the Benesi-Hildebrand equation. The detection limit for Cr3+ is 0.5 x 10(-6) M. The developed method has been used for speciation studies in a fast and environment friendly way using least amounts of samples, non-hazardous chemicals and solvents.
Doi 10.1039/c2ay25693b
Wosid WOS:000309238300014
Is Certified Translation No
Dupe Override No
Comments Source: Web of Science WOS:000309238300014
Is Public Yes