Synthesis and structural characterization of bis-cyclometalated complexes [M(ptpy)(2)(S2COCH3)] (M = Rh, Ir; ptpy=2-(p-tolyl)pyridinato)
Graf, M; Boettcher, HC; Suenkel, K
| HERO ID | 1447322 |
|---|---|
| In Press | No |
| Year | 2013 |
| Title | Synthesis and structural characterization of bis-cyclometalated complexes [M(ptpy)(2)(S2COCH3)] (M = Rh, Ir; ptpy=2-(p-tolyl)pyridinato) |
| Authors | Graf, M; Boettcher, HC; Suenkel, K |
| Journal | Inorganica Chimica Acta |
| Volume | 394 |
| Page Numbers | 363-366 |
| Abstract | The synthesis of the bis-cyclometalated complexes [M(ptpy) (2)(S2COCH3)] (M = Rh, 1; M = Ir, 2; ptpy = 2-(p-tolyl)pyridinato) from [{M(mu-Cl)(ptpy)(2)}(2)], carbon disulfide and sodium methanolate as the base are described. Compound 1 and 2, respectively, were crystallized from dichloromethane/methanol and the molecular structures of both complexes were confirmed by single-crystal X-ray diffraction studies (both monoclinic, P2 (1)/c). The emission spectrum of 1 exhibited the new compound as a red-emitting complex. (C) 2012 Elsevier B. V. All rights reserved. |
| Doi | 10.1016/j.ica.2012.08.032 |
| Wosid | WOS:000311492900047 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Source: Web of Science WOS:000311492900047 |
| Is Public | Yes |
| Keyword | Cyclometallated complexes; Xanthate; Rhodium; Iridium; Crystal structure |