Mixed complexes in the system Eu3+-8-quinolinol-phenanthroline

Farah, K; Raouf, MWA; Tadros, N; Kandil, AT

HERO ID

1179925

Reference Type

Journal Article

Year

1999

Language

English

HERO ID 1179925
In Press No
Year 1999
Title Mixed complexes in the system Eu3+-8-quinolinol-phenanthroline
Authors Farah, K; Raouf, MWA; Tadros, N; Kandil, AT
Journal Separation Science and Technology
Volume 34
Issue 5
Page Numbers 793-804
Abstract The extraction of Eu3+ from an aqueous perchlorate medium of constant ionic strength (0.1 M NaClO4) was studied at different temperatures by 8-quinolinol (HQ) in benzene, carbon tetrachloride, and chloroform, and by a mixture of 8-quinolinol and 1,10-phenanthroline (Phen), allowing for elucidation of the thermodynamic parameters and the mechanism of extraction of the species formed. The results indicated that the extraction is enhanced by adduct formation in the organic phase, and that the main extracted species were EuQ(3). 2HQ, EuQ(3). 2HQ . Phen, and EuQ(3). 2HQ . 2Phen.
Doi 10.1081/SS-100100682
Wosid WOS:000079962600007
Url https://www.scopus.com/inward/record.uri?eid=2-s2.0-0344759152&doi=10.1081%2fSS-100100682&partnerID=40&md5=8085bddfccf39e985ab4a7a40b1db8bd
Is Certified Translation No
Dupe Override No
Comments Source: Web of Science 000079962600007
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Language Text English
Is Qa No