Transport of Metal Ions through Cellulose Fiber Supported Solid Membrane into Tributyl Phosphate Containing Mixed Solvents

Gaikwad, AG

HERO ID

1108026

Reference Type

Journal Article

Year

2011

Language

English

HERO ID 1108026
In Press No
Year 2011
Title Transport of Metal Ions through Cellulose Fiber Supported Solid Membrane into Tributyl Phosphate Containing Mixed Solvents
Authors Gaikwad, AG
Journal Chemical and Biochemical Engineering Quarterly
Volume 25
Issue 4
Page Numbers 425-431
Abstract A novel cation exchange fiber supported solid membrane was developed for transport of cobalt, manganese and nickel metal ions. Fiber supported solid membrane was prepared by chemically modifying the cellulose fibers with citric acid. In the fiber supported solid membrane, the diffusion by capillary action by keeping the liquid phase in the porous solid fiber and ion exchange mechanism were used for the effective transport of metal ions. The experimental variables examined were concentration of metal ions (10(-2) to 10(-4) mol L-1) in the source solution, mixed solvent composition (phi = 20 % TBP, acetone or tetrahydrofuran or 1,4-dioxane or methanol or ethanol or 2-propanol 10 to 60 % and HCl (1 to 2 mol L-1) in the receiving phase and stirring speed (40-120 rpm) of the bulk source and receiving phase. The enrichment of concentration of cobalt, manganese and nickel metal ions was observed from the dilute solutions.
Wosid WOS:000300274300002
Url <Go to ISI>://WOS:000300274300002
Is Certified Translation No
Dupe Override No
Comments Source: Web of Science 000300274300002
Is Public Yes
Language Text English
Keyword Cobalt; manganese and nickel metal ions; fiber supported solid membrane; binary of mixtures of metal ions; ion exchange; extraction; stripping
Is Qa No