Direct Observation of a Carbene-Alcohol Ylide
Xue, J; Luk, HL; Platz, MS
| HERO ID | 1040309 |
|---|---|
| In Press | No |
| Year | 2011 |
| Title | Direct Observation of a Carbene-Alcohol Ylide |
| Authors | Xue, J; Luk, HL; Platz, MS |
| Journal | Journal of the American Chemical Society |
| Volume | 133 |
| Issue | 6 |
| Page Numbers | 1763-1765 |
| Abstract | Carboethoxycarbene reacts with methanol-OD to form an ylide. The formation and decay of this ylide was monitored by ultrafast time-resolved IR spectroscopy. The formation and decay of the ylide is linearly dependent on the concentration of methanol-OD in acetonitrile with second-order rate constants of ylide formation (8.4 × 10(9) M(-1) s(-1)) and decay (1.4 × 10(9) M(-1) s(-1)). Similar results were obtained with 1-butanol. |
| Doi | 10.1021/ja111029g |
| Pmid | 21265530 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Source: Web of Science 000287831800041 |
| Is Public | Yes |
| Language Text | English |
| Is Qa | No |