Simultaneous determination of mono- and disubstituted polyfluoroalkyl phosphates in drinking water by liquid chromatography-electrospray tandem mass spectrometry
Ding, H; Peng, H; Yang, M; Hu, J
HERO ID
1038497
Reference Type
Journal Article
Year
2012
Language
English
PMID
| HERO ID | 1038497 |
|---|---|
| In Press | No |
| Year | 2012 |
| Title | Simultaneous determination of mono- and disubstituted polyfluoroalkyl phosphates in drinking water by liquid chromatography-electrospray tandem mass spectrometry |
| Authors | Ding, H; Peng, H; Yang, M; Hu, J |
| Journal | Journal of Chromatography A |
| Volume | 1227 |
| Page Numbers | 245-252 |
| Abstract | A sensitive liquid chromatography-electrospray tandem mass spectrometry method was established for the simultaneous determination of five monosubstituted polyfluoroalkyl phosphates (monoPAPs) and eight disubstituted polyfluoroalkyl phosphates (diPAPs) in drinking water. Complete separation and good retention for 13 polyfluoroalkyls phosphates (PAPs) were achieved with a Waters ACUITY UPLC BEH C8 column using a mixture of methanol/water containing 0.1% NH₄OH as the mobile phases. Extraction of drinking water samples was performed on weak anion exchange (WAX) cartridges, and the recoveries of target compounds were from 65 to 110%. The limits of quantization (LOQs) for 13 analytes were in the range of 0.4-40 ng/L. This method was applied to analyze the PAPs in drinking water samples from three cities in China. Of the 13 PAPs, six PAPs including 6:2 monoPAP (13.0 ng/L), 8:2 monoPAP (3.6 ng/L), 10:1 monoPAP (4.3-70.3 ng/L), 10:2 monoPAP (1.4-5.6 ng/L), 8:2 diPAP (0.10 ng/L), and 10:1 diPAP (0.8-3.8 ng/L) were detected. |
| Doi | 10.1016/j.chroma.2012.01.004 |
| Pmid | 22284536 |
| Wosid | WOS:000301563700027 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Source: Web of Science 000301563700027 |
| Is Public | Yes |
| Language Text | English |
| Keyword | Disubstituted polyfluoroalkyl phosphates; Monosubstituted polyfluoroalkyl; phosphates; WAX cartridge; LC-MS/MS; Drinking water |